By G.W. Cullen, E. Kaldis and R.L. Parker (Eds.)
Read or Download Vapour Growth and Epitaxy. Proceedings of the Third International Conference on Vapour Growth and Epitaxy, Amsterdam, The Netherlands, 18–21 August 1975 PDF
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Additional info for Vapour Growth and Epitaxy. Proceedings of the Third International Conference on Vapour Growth and Epitaxy, Amsterdam, The Netherlands, 18–21 August 1975
Cd r- CQ Tf G °^ NUC/2 C TJ G2 CO 33 34 MeAl3Cl12,with H. Schäfer / Complexes in vapour phase and their implications for vapour growth In 2 UCl 10 , Tl2ThCl6, observed [13,14]. In these reactions, the solid phase is transported in the direction of the arrow, and is deposited as well formed crystals : T1U2C19, Beln2Cl8; Me = Nd,Cr(Rh). It follows from the measurements of Dewing  and Papatheodorou  that AH® « 10 kcal and AS** ~ ~ 10 cal/deg mol for eq. (5), with striking regularity : MeCl2(s) + A12C16 (g) = MeAl2Cl8 (g).
Estimates of the effects of these gravity perturbations in terms of buoyancy, pressure waves and shear between the trans port ampoule and gas phase indicate that their con tributions to the mass transport rates in micro-gravity are negligible. In view of the highly unexpected transport rates observed in space, continued theoretical and experi mental studies are in progress in order to explain these unusual transport phenomena. 3. 1. Optical microscopy A'comparison of representative GeTe crystals ob tained in space (SL3, C) and on earth shows the im- vv Fig.
Introduction 2. Experimental technique There are well-known experimental studies on the synthesis of diamond in the thermodynamic stability region under superhigh pressure and at high tempera tures. The research in the diamond synthesis within the region of its thermodynamic metastability [1—4] began to develop practically simultaneously. The layers of synthetic diamond are usually grown on the natural diamond single crystals by thermal de composition of carbonaceous gases at pressures near to and lower than atmospheric pressure.