By David W Allen; David Loakes; John C Tebby
Organophosphorus Chemistry offers a finished and important overview of the new literature. insurance contains phosphines and their chalcogenides, phosphonium salts, low coordination quantity phosphorus compounds, penta- and hexa- coordinated compounds, quiquevalent phosphorus acids, nucleotides and nucleic aicds, ylides and comparable compounds, phosphazenes and the appliance of actual tools within the research of organophosphorus compounds. this can be the fortieth in a sequence of volumes which first seemed in 1970 below the editorship of Stuart Trippett and which coated the literature of organopho. learn more... content material: I-iv; v-viii; ix-xii; xiii-xiv; 1-55; 56-88; 89-112; 113-146; 147-168; 169-250; 251-321; 322-348; 349-384; 385-412. summary: Organophosphorus Chemistry offers a entire and demanding overview of the hot literature. assurance comprises phosphines and their chalcogenides, phosphonium salts, low coordination quantity phosphorus compounds, penta- and hexa- coordinated compounds, quiquevalent phosphorus acids, nucleotides and nucleic aicds, ylides and comparable compounds, phosphazenes and the appliance of actual tools within the research of organophosphorus compounds. this is often the fortieth in a chain of volumes which first seemed in 1970 below the editorship of Stuart Trippett and which coated the literature of organopho
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Additional info for Organophosphorus Chemistry Vol. 40
468 Studies of the generation and reactivity of phosphinidene species (RP:), phosphorus analogues of carbenes, have also continued to be of interest. 472 The chemistry of phosphinidene-metal complexes has also continued to be of interest. 486 4 Phosphirenes, phospholes and phosphinines Interest in potentially aromatic heterocyclic systems has continued, with most work again relating to the chemistry of phospholes. Activity in the phosphirene area has continued with the appearance of several papers on the chemistry of both the parent phosphirene and related heterophosphirene systems.
327 Applications of tertiary phosphine-positive halogen reagents in the synthesis of ﬂuorocarbons include a route to CF3-containing bromoallenes (108) from related propargylic alcohols using Ph3P – tetrabromomethane,328 and the development of chain extension reactions involving triphenylphosphine, tribromoﬂuoromethane and a diﬂuoromethylene alkene that involve the capture of the intermediate dibromoﬂuoromethide anion. 3 Nucleophilic attack at other atoms. 330 Amine- and phosphine-borane adducts prepared from aziridine, phosphirane, cyclopropylamines and cyclopropylphosphines have been compared using photoelectron spectroscopy and computational techniques.
368 Cleavage of disulﬁde bonds by tertiary phosphines has again attracted attention. 370 Troﬁmov’s group has published a series of papers on the reactions of secondary phosphines with sulfur or selenium, in the presence of amine bases, that lead to the formation of dithiophosphinate371 and diselenophosphinate372 salts. 374 Interest has also continued in the Mitsunobu and Staudinger reactions, in which nucleophilic attack by phosphorus at nitrogen is the initial step. Although there have been no reports describing more fundamental mechanistic aspects of these reactions, their applications in synthetic chemistry have continued to develop.