Dynamics of reactive systems Part 2 Heterogeneous combustion by A. L. Kuhl

By A. L. Kuhl

Papers from the colloquium held August 1987. the 1st a part of the two-volume set covers flames: ignition dynamics, flame chemistry, diffusion flames in shear circulation, dynamics of flames, combustion diagnostics. half is targeted on heterogeneous combustion and functions.

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A photomultiplier (Hamamatsu R106) is used as a photodetector element. View is confined in a circle of 10 mm diameter around the axis. 3) Visible- and near-IR-band (V and IR) emissions. Either a visible light transmission filter (Japan Vacuum Optics, cold filter CF-B) or a near-IR light transmission filter (Japan Vacuum Optics, cold mirror CM) is placed in front of the photodetector unit of the wide-band photodetector system in item 1. 2b. Every curve is normalized by its peak value. UV involves OH(0,0) band and V includes CH(0,0), CH(2,2), and C (0,0) bands as well as continuous solid emissions, whereas IK includes the absorption band of steam around 930 nm and continuous solid emissions.

Ideally, a combination of both approaches would be desirable: larger-diameter shock tube to decrease the wall boundary layer effects and more sensitive diagnostics to permit the requisite greater dilution so that steady conditions are a safe assumption for data analysis. In Fig. 2 the same temperature dependence of TP for all mixtures of the same oxygen concentration (mixtures 3, 4, 5, and 6) can be seen. The absorption profile TJ are in good agreement with the predictions from the correlation formulas of Lifshitz et al.

As was shown by Rabinowitz et al [1986a] the calculated values of r and Qm gave similar values and varied in similar ways with changes in mixture composition for the different detailed chemical kinetic mechanisms they considered; therefore, it may be expected that the proportionality constant will not differ greatly among detailed chemical kinetic mechanisms. TWO-ZONE MODEL OF ENERGY RELEASE 27 Conclusions The existence of an intrinsic relationship between the ignition delay and the rate of reaction zone energy release has been demonstrated.

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