By James F. Shackelford, Robert H. Doremus
"Ceramic and Glass fabrics: constitution, houses and Processing" is a concise and finished advisor to the foremost ceramic and glass fabrics utilized in sleek expertise. each one bankruptcy makes a speciality of the structure-property relationships for those very important fabrics and expands the reader's figuring out in their nature by means of concurrently discussing the expertise in their processing equipment. In every one case, the ensuing realizing of the modern purposes of the fabrics offers insights as to their destiny roles in 21st century engineering and know-how. prepared to be a pragmatic and accomplished source, each one bankruptcy is devoted to a particular fabric akin to: alumina, mullite, sillimanite minerals, aluminates, quartz and silicas, refractory oxides, clays, concrete and cement, lead compounds, and zirconia. Written by way of foreign authors in fabrics technology and engineering, "Ceramic and Glass fabrics: constitution, homes and Processing" is a useful reference for complex undergraduates, graduate scholars, and dealing pros in a variety of clinical fields.
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Extra info for Ceramic and Glass Materials: Structure, Properties and Processing
Doremus Table 20 Gibbs Free energies of reactions of metals with 1 atm. of oxygen at 1,000°C from [28, 29, 46–48] −∆G Solid metals −∆G (kJ mol−1) Liquid metals Y Zr Ti Si V Mn Cr One atm. 6 444 418 326 At 1,000°C the Gibbs free energy for this reaction is about −2133 kJ mol−1, showing a strong tendency to react. Reactions of the gases H2, H2O, CO, and CO2 with alumina can be deduced from the reactions: Al 2 O3 + 3H 2 = 2 Al + 3H 2 O (16) Al 2 O3 + 3CO = 2 Al + 3CO2 (17) At equilibrium at 1,000°C the ratio of H2/H2O is about 1010 and CO/CO2 about 2(10)10.
Eur. Ceram. Soc. 21, 2541–2562 (2001). 58. T. N. -I. A. Parthasarathay, Anisotropic grain growth and microstructural evolution of dense mullite above 1550°C, J. Am. Ceram. Soc. 83 (1), 204–210 (2000). Chapter 3 The Sillimanite Minerals: Andalusite, Kyanite, and Sillimanite Richard C. SiO2 sillimanite minerals (anadlusite, kyanite, and sillimanite) are described. Their P–T diagram is discussed. The structural differences among the three are reviewed, emphasizing the coordination of the Al3+ cations that link the double octahedral chains within the structures.
R. Y. L. J. Perrotta, Conversion of diaspore to corundum, J. Am. Ceram. Soc. 80, 2677–80 (1997). 9. L. S. Patent 3,026,210, March 20 (1967). 1 Alumina 25 10. J. Klug, S. H. Doremus, Alumina-silica phase diagram in the mullite region, J. Am. Ceram. Soc. 70, 750–759 (1987). 11. N. Bunting, Phase equilibrium in the system Cr3O3–Al2O3, Bur. Stand. J. Res. 6, 947–949 (1931). 12. M. R. F. McMurdie, Phase Diagrams for Ceramists, Vol. I–XIII, The American Ceramic Society, 1964–2002. 13. M. E. Barks, Subsolidus phase equilibrium in Al2O3–Cr2O3, Nature, 235, 118–119 (1972).